The rate-determining step in the epoxidation of alkenes by the cytochrome P-450 model manganese(III) porphyrin/hypochlorite
✍ Scribed by A. W. van der Made; P. M. F. C. Groot; R. J. M. Nolte; W. Drenth
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 457 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0165-0513
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## Abstract The effect of some nitrogen bases on the oxygenation of tetralin by sodium periodate, catalyzed by Mn(TPP)OAc, was evaluated. A series of eight bases, including imidazole, pyridine, and quinuclidine, was used. Binding of axial ligand to the four‐coordinate Mn(III)‐center influenced the