✦ LIBER ✦
Effects of some Nitrogen Bases on the Oxygenation of Tetralin with Sodium Periodate Catalyzed by Manganese(III) meso-Tetraphenylporphyrin as a Model Compound of Cytochrome P-450
✍ Scribed by Tayebee Reza
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 57 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0256-7660
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✦ Synopsis
Abstract
The effect of some nitrogen bases on the oxygenation of tetralin by sodium periodate, catalyzed by Mn(TPP)OAc, was evaluated. A series of eight bases, including imidazole, pyridine, and quinuclidine, was used. Binding of axial ligand to the four‐coordinate Mn(III)‐center influenced the efficiency and selectivity of the catalytic oxygenation system.