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The Rate and Equilibrium Constants for the Reaction NO 3• + Cl - ⇄ NO 3- + Cl • in Aqueous Solutions

✍ Scribed by Poskrebyshev, G. A.; Huie, R. E.; Neta, P.

Book ID
127209123
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
148 KB
Volume
107
Category
Article
ISSN
1089-5639

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Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 Ϯ 2 K 740 Ϯ 5 torr pressure are: Ϫ11 3 Ϫ1 Ϫ1 Ϫ18 3 k ϭ (3.9 Ϯ 1.