The angular and velocity distribution of the ICl product from reaction (1) at 4.5 kcal/mol collision energy has been obtained by Cross and Blais in a crossed-molecular-beam study [1]. It was concluded that the angular distribution is consistent with that arising from short range attractive forces an
Determinations of the rate constants of the reactions Cl + N3Cl and N3 + NO at 295 K
β Scribed by John Brunning; Michael A.A. Clyne
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 439 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The rate constant for the reaction of CI with CHCI, was measured relative to the CI reaction with Cti, and CH,CI using long path FTIR. The measured rate constant at 298 K and 1 atm total pressure was ( I 21 ? 0 13) X 10-"cm3 molecule-'s-' ( 2 ~1 , about 60%larger than the currently recommended value
The rate constants for the reaction of NO, radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3pentadiene, trans,trans-2,4bexadiene, and LEcyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constants were
## Abstract The photooxidations of __n__βbutyraldehyde initiated by Cl atom were carried out at room temperature (298 Β± 2K) and 1 atm pressure. The rate coefficient for the reactions of Cl atom with __n__βbutyraldehyde was determined as __k__ = (2.04 Β± 0.36) Γ 10^β10^ cm^3^ molecule^β1^ s^β1^ by us
Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe
Mass spectrometric studies of the ions present in Hz/Oz/N2 flames with potassium and chlorine added have demonstrated that ionization can occur in the forward steps of K + Cl ", K+ f Cl-(II), KC1 t &IS K+ -L Cl-f Vx (IV). where >I k any third body. Variations of [K+] with time in these systems have