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The pyrimidine-iodine interaction; a study of complex formation by NMR of oriented molecules

✍ Scribed by N. Suryaprakash; R. Ugolini; P. Diehl

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 241 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260291009

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✦ Synopsis

Abstract

The interaction of pyrimidine with iodine when both are dissolved in a liquid crystal solvent has been studied. The considerable changes observed in the degrees of order of pyrimidine can be quantitatively attributed to complex formation between the nitrogen atoms and iodine along axes forming angles of 30° with the nitrogen–nitrogen axis and in the molecular plane. The complex formation does not affect measurably the proton and carbon positions of pyrimidine.

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