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A NMR reverse diffusion filter for the simplification of spectra of complex mixtures and the study of drug receptor interactions

✍ Scribed by M. Vega-Vázquez; J. C. Cobas; F. F. Oliveira de Sousa; M. Martin-Pastor


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
204 KB
Volume
49
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

A reverse diffusion filter NMR experiment (Drev) is proposed for the study of small molecules in binding with macromolecules. The filtering efficiency of Drev to eliminate the signals of the macromolecule is shown to be superior to conventional transverse relaxation filters at least for macromolecules containing a significant fraction of flexible residues. The Drev filter was also a useful complement for ligand‐based NMR screening in combination with saturation transfer difference experiments. Copyright © 2011 John Wiley & Sons, Ltd.