✦ LIBER ✦

The propagation of exothermic reactions in solid systems, part II. Heats of reaction and rates of burning

✍ Scribed by Spice, J. E. ;Staveley, L. A. K.

Publisher: Wiley (John Wiley & Sons)
Year: 1949
Weight: 911 KB
Volume: 68
Category: Article
ISSN: 0368-4075
DOI: 10.1002/jctb.5000681205

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✦ Synopsis

Abstract

Measurements have been made of the linear rate of the self‐propagating reaction and of the heat of this reaction in compressed binary solid mixtures of an oxidizing and a reducing agent. The thermochemical results have been used to draw conclusions about the chemistry of the reactions involved and about the maximum temperatures reached during burning. The dependence of the rate of reaction on the heat it evolves is discussed, and an explanation given of the fact that the rate usually reaches its maximum at a higher (and never at a lower) percentage of reducing agent than that at which the heat of burning has its greatest value.

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