✦ LIBER ✦

Rate constants of elementary reactions in the high temperature system of nitric oxide and hydrogen

✍ Scribed by H. Ando; T. Asaba

Publisher: John Wiley and Sons
Year: 1976
Tongue: English
Weight: 639 KB
Volume: 8
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550080208

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✦ Synopsis

The consumption of nitric oxide in the shock-heated nitric oxide, hydrogen, and argon system had been studied and modeled as the chain-branching process containing the reaction H + NO Through the computer simulation method the authors clarified the role of the initiation reaction HI + NO -H N O + H (kl) in the system and obtained the rate constants of kl and k3 as k i = 10 13~f0.15 exp (-55.2 kcal/RT) and k3 = 1013.7*0.15 exp (-48.7 kcal/RT) (cm3/mole.sec), respectively. k i was one order larger than the value obtained in the flame experiment by Halstead and Jenkins.

N + OH (k3) as a slow-branching step.

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