Part II: Reaction rate studies and the analysis of batch esterification in two phase systems
- Publisher
- American Institute of Chemical Engineers
- Year
- 1981
- Tongue
- English
- Weight
- 621 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0001-1541
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✦ Synopsis
Abstract
The kinetics of the esterification of n‐butyl alcohol with acetic acid has been studied experimentally in concentrated solutions at near ambient temperature in the presence of a sulphuric acid catalyst and the rate constants for the forward and reverse reaction determined.
The rate data obtained from the homogeneous system has been applied to analyse the performance of a batch‐extractive reactor using n‐heptane as solvent. The rate of mass transfer of the ester was found to be significant and when introduced in a model of the reaction process gave good agreement with the experimental results.
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