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Part II: Reaction rate studies and the analysis of batch esterification in two phase systems


Publisher
American Institute of Chemical Engineers
Year
1981
Tongue
English
Weight
621 KB
Volume
27
Category
Article
ISSN
0001-1541

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✦ Synopsis


Abstract

The kinetics of the esterification of n‐butyl alcohol with acetic acid has been studied experimentally in concentrated solutions at near ambient temperature in the presence of a sulphuric acid catalyst and the rate constants for the forward and reverse reaction determined.

The rate data obtained from the homogeneous system has been applied to analyse the performance of a batch‐extractive reactor using n‐heptane as solvent. The rate of mass transfer of the ester was found to be significant and when introduced in a model of the reaction process gave good agreement with the experimental results.


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