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The production of metallocarbohedrenes by the direct laser vaporization of the carbides of titanium and zirconium

โœ Scribed by S.F. Cartier; B.D. May; B.J. Toleno; J. Purnell; S. Wei; A.W. Castleman Jr.

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
379 KB
Volume
220
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Metallocarbohedrenes (Met-Cars) of titanium and zirconium have been produced by the direct laser vaporization of their respective pure carbides. Time-of-flight mass spectra of both ionic and neutral metallocarbohedrenes formed in the laser-induced plasma are presented and compared to spectra of the same systems generated under laser vaporization/molecular beam conditions. Potential mechanisms of formation of these clusters are presented and discussed.

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