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The problem of spin triplet states of iron(II) in 57Fe Mössbauer emission spectra

✍ Scribed by E. König; P. Gütlich; R. Link

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 310 KB
Volume: 15
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)80175-1

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✦ Synopsis

Bath thcoreticai and experimental evidence is presented to demonstrate that doublet C previously observed in the j7Fe hfb'ssbauer emission spectrum of [Co(phen)3] CCIOJ)~.XI~O is mcst uniikely to originate in 3 spin triplet pound stare of iron(X). Rather doublets C and B are assigned to the intact [ "Fc(phenj3 ] (C104)~ complex and to J. complex involving one defect phen ligand, respectively. * To &r&~ bls to the stzmdard xtural iron, add +o.cl45 ITun %x-~.

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