Magnetic, 57Fe Mössbauer, and IR Monitoring of the Thermal Spin Transition in a New Family of Iron(II) Spin-Transition Complexes
✍ Scribed by Arno F. Stassen; Matthias Grunert; Eva Dova; Martin Müller; Peter Weinberger; Günter Wiesinger; Henk Schenk; Wolfgang Linert; Jaap G. Haasnoot; Jan Reedijk
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 307 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)
## Abstract A dinuclear iron(II) complex containing the new pyridyl bridging ligand, 2,5‐di(2′,2′′‐dipyridylamino)pyridine (ddpp) has been synthesised and characterised by single‐crystal X‐ray diffraction, magnetic susceptibility and Mössbauer spectral methods. This compound, [Fe~2~(ddpp)~2~(NCS)~4