The Nature of Spin Crossover and Coordination Core Distortion in a Family of Binuclear Iron(II) Complexes with Bipyridyl-Like Bridging Ligands

Spin Crossover in a Family of Iron(II) C

Spin Crossover in a Family of Iron(II) Complexes with Hexadentate ligands: Ligand Strain as a Factor Determining the Transition Temperature

✍ Galina S. Matouzenko; Serguei A. Borshch; Erwann Jeanneau; Mark B. Bushuev 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 460 KB 👁 2 views

## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)