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The Pressure Dependence of the OH Radical Yield from Ozone−Alkene Reactions

✍ Scribed by Fenske, Jill D.; Hasson, Alam S.; Paulson, Suzanne E.; Kuwata, Keith T.; Ho, Andy; Houk, K. N.

Book ID: 127324749
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 243 KB
Volume: 104
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp001100u

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Absolulc KIIC constants for the rcac11on ofOH WIII acctylcnc wcrc dctcrmmcd at 297 and 419 K for thu 101.d pru~rc\ ol'20-403 Torr usmg a flash photolysa-rcsonancc lluorcsccnre tcchmquc The rate coclTic~cnt k was found to bc pwrurc dcpcndcnt below 200 Torr at both 297 and 429 K, but \\a m the high-pr