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The Preparation of Organolithium Compounds by the Transmetalation Reaction. IV. Some Factors Affecting the Transmetalation Reaction

✍ Scribed by Seyferth, Dietmar.; Weiner, Michael A.

Book ID
123614668
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
589 KB
Volume
84
Category
Article
ISSN
0002-7863

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## Abstract Redox transmetallation reactions between trimethyltin compounds, SnMe~3~L [L = 3,5‐diphenylpyrazolate (Ph~2~pz), 2,6‐di‐__tert__‐butyl‐4‐methylphenolate (OAr), or C~6~F~5~] and lanthanoid metals have yielded [Ln(Ph~2~pz)~2~(DME)~2~] (Ln = Eu, Yb), [Ln(Ph~2~pz)~3~(DME)~2~] (Ln = Y, La, N