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Preparation of Organolithium Compounds by the Transmetalation Reaction. III. Allyllithium and Methallyllithium 1,2a

โœ Scribed by SEYFERTH, DIETMAR; WEINER, MICHAEL A.

Book ID
121356103
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
541 KB
Volume
26
Category
Article
ISSN
0022-3263

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Organolithium anions, generated either by deprotonation or lithium-bromine exchange, when quenched with 2,2,2-trifluoro-l-iodoethane produce cleanly the synthetically useful iodoarenes, iodoalkenes and iodoalkynes.