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A simple preparation of iodoarenes, iodoalkenes and iodoalkynes by reaction of organolithiums with 2,2,2-trifluoro-1-iodoethane

✍ Scribed by Ian J. Blackmore; Andrew N. Boa; Ernest J. Murray; Michael Dennis; Simon Woodward

Book ID: 104262126
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 129 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01343-x

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✦ Synopsis

Organolithium anions, generated either by deprotonation or lithium-bromine exchange, when quenched with 2,2,2-trifluoro-l-iodoethane produce cleanly the synthetically useful iodoarenes, iodoalkenes and iodoalkynes.

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