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The Preparation and Properties of 1,2-Diethyl-1,2-bis-(dimethylamino)- and 1,2-Bis-(dimethylamino)-1,2-diphenyldiborons

✍ Scribed by Brotherton, R. J.; Manasevit, H. M.; McCloskey, A. L.


Book ID
126938839
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
688 KB
Volume
1
Category
Article
ISSN
0020-1669

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Synthesis, structure and basicity of 1,9
✍ Heinz A. Staab; Matthias HΓΆne; Claus Krieger πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 295 KB

In the context of studies on bis(dialkylamino)arenes with neighbouring amino functions the title compounds 5 and 6 were synthesized. Their structures and those of the monoprotonated cations Sa and 6a were determined by X-ray analysis. The strong basicities of 5 and 6 (pKa = 11.9 and 11.8 f 0.1) are