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1,1-Bis(dimethylamino)-2,2,2-trifluoroethane, a Readily-Available Precursor to the Novel Fluorinated Building Block 1,1-Bis(dimethylamino)-2,2-difluoroethene

✍ Scribed by Xu, Yuelian; Dolbier,, William R.; Rong, Xiao X.


Book ID
121420195
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
167 KB
Volume
62
Category
Article
ISSN
0022-3263

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## Abstract The title compound **4** is generated from the phosphoric amide **5** in tetrahydrofuran with butyllithium. The lithium reagent **4** is stable at room temperature; its reactions with electrophiles furnish the products **6–22**, **26**, **27**, see __Table 1__ and the __Scheme__. A seco