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Head-to-head versus head-to-tail dimerizations of transient silenes—the synthesis and reactivity of 2-(8-dimethylamino-1-naphthyl)- and 2-(4-dimethylamino-1-naphthyl)-1,1-bis(trimethylsilyl)silene

✍ Scribed by Douglas Hoffmann; Helmut Reinke; Hartmut Oehme


Book ID
108354807
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
192 KB
Volume
585
Category
Article
ISSN
0022-328X

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Head-to-Head versus Head-to-Tail Dimeriz
✍ Kathleen Schmohl; Matthias Blach; Helmut Reinke; Rhett Kempe; Hartmut Oehme 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 363 KB 👁 3 views

The regiospecifity of the dimerization of the transient 2-(2-cyclobutane (13) was obtained. 1,1-Bis(trimethylsilyl)-2-(2,4,6-trimethoxyphenyl)silene (18), similarly made by a methoxyphenyl)-1,1-bis(trimethylsilyl)silene (6), synthesized by base-initiated trimethylsilanolate elimination from (2-modif