ChemInform Abstract: Head-to-head versus Head-to-tail Dimerizations of Transient Silenes. The Synthesis and Reactivity of 2-(8-Dimethylamino-1-naphthyl)- and 2-(4-Dimethylamino-1-naphthyl)-1,1-bis(trimethylsilyl)silene.

Head-to-Head versus Head-to-Tail Dimeriz

Head-to-Head versus Head-to-Tail Dimerizations of Transient Silenes – The Solvent-Dependent Regiospecifity of the Dimerization of 2-(2-Methoxyphenyl)-1,1-bis(trimethylsilyl)silene

✍ Kathleen Schmohl; Matthias Blach; Helmut Reinke; Rhett Kempe; Hartmut Oehme 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 363 KB 👁 3 views

The regiospecifity of the dimerization of the transient 2-(2-cyclobutane (13) was obtained. 1,1-Bis(trimethylsilyl)-2-(2,4,6-trimethoxyphenyl)silene (18), similarly made by a methoxyphenyl)-1,1-bis(trimethylsilyl)silene (6), synthesized by base-initiated trimethylsilanolate elimination from (2-modif