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ChemInform Abstract: 1,1-Bis(dimethylamino)-2,2,2-trifluoroethane, a Readily-Available Precursor to the Novel Fluorinated Building Block 1,1-Bis( dimethylamino)-2,2-difluoroethene.

โœ Scribed by Y. XU; W. R. JUN. DOLBIER; X. X. RONG


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diverse Cycloadditi
โœ Y. XU; W. R. JUN. DOLBIER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 2 views

Diverse Cycloaddition Chemistry Leading to Overall Michael Addition in the Reactions of 1,1-Bis(dimethylamino)-2,2-difluoroethene with ฮฑ,ฮฒ-Unsaturated Aldehydes, Ketones, Esters, and Nitriles. -The freshly prepared difluoro ketene aminal (I) reacts with ฮฑ,ฮฒ-unsaturated aldehydes or ketones via [4 +