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The Polyol Domain of Amphidinol 3. A Stereoselective Synthesis of the Entire C(1)−C(30) Sector

✍ Scribed by Paquette, Leo A.; Chang, Shuh-Kuen


Book ID
125897516
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
114 KB
Volume
7
Category
Article
ISSN
1523-7060

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The macrocyclic domain of phorboxazole A
✍ David R Williams; Michael P Clark 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 192 KB

A stereoselective synthesis of the C1~232 macrocyclic domain of phorboxazole A is described. Key steps have examined the convergent linkage of two major components for the formation of the CI9--C20 (E)-alkene, and the subsequent intramolecular (Z)olefination at C2-C 3 for ring closure of the macrocy