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The Pinacol Rearrangement in the Heterocyclic Series. III. Numerical Migratory Aptitudes

✍ Scribed by Kegelman, Matthew R.; Brown, Ellis V.


Book ID
126034822
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
407 KB
Volume
76
Category
Article
ISSN
0002-7863

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The Migratory Aptitude of the Ethoxycarb
✍ Jacques Kagan; Dalmacio A. Agdeppa Jr.; S. P. Singh πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 German βš– 192 KB πŸ‘ 2 views

## Abstract The migratory aptitude of the ethoxycarbonyl group in the pinacol rearrangement was deduced from the structure of the products observed after treatment of 2‐substituted 2,3‐dihydroxy‐3‐phenylbutyrates with fluorosulfonic acid at 0Β° for 3 minutes. The migratory aptitude of ethoxycarbonyl