Theoretical study of the reaction mechanism and migratory aptitude of the pinacol rearrangement
β Scribed by Nakamura, Kensuke; Osamura, Yoshihiro
- Book ID
- 120506318
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 930 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The migratory aptitude of the ethoxycarbonyl group in the pinacol rearrangement was deduced from the structure of the products observed after treatment of 2βsubstituted 2,3βdihydroxyβ3βphenylbutyrates with fluorosulfonic acid at 0Β° for 3 minutes. The migratory aptitude of ethoxycarbonyl
## Abstract The neopentyl and the pinacol rearrangements as examples of WagnerβMeerwein rearrangements were investigated by the use of DFT calculations. As the first reaction, a model of neopentyl chloride (1b) and (H~2~O)~12~ was employed. In the reaction, the patterns of Cο£ΏCl scission, methyl mig