𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theoretical study of the reaction mechanism and migratory aptitude of the pinacol rearrangement

✍ Scribed by Nakamura, Kensuke; Osamura, Yoshihiro


Book ID
120506318
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
930 KB
Volume
115
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


The Migratory Aptitude of the Ethoxycarb
✍ Jacques Kagan; Dalmacio A. Agdeppa Jr.; S. P. Singh πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 German βš– 192 KB πŸ‘ 2 views

## Abstract The migratory aptitude of the ethoxycarbonyl group in the pinacol rearrangement was deduced from the structure of the products observed after treatment of 2‐substituted 2,3‐dihydroxy‐3‐phenylbutyrates with fluorosulfonic acid at 0Β° for 3 minutes. The migratory aptitude of ethoxycarbonyl

Theoretical study of the role of solvent
✍ Shinichi Yamabe; Noriko Tsuchida; Shoko Yamazaki πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 978 KB

## Abstract The neopentyl and the pinacol rearrangements as examples of Wagner–Meerwein rearrangements were investigated by the use of DFT calculations. As the first reaction, a model of neopentyl chloride (1b) and (H~2~O)~12~ was employed. In the reaction, the patterns of Cο£ΏCl scission, methyl mig