Regiospeciflcity of pyrrole subunit 0~04 oxidation in porphyrins is affected significantly by the presence of electron-withdrawing groups on the macrocycle. the oxidation taking place at the subunit in the quadrant opposite to the electronegative group. Migratory aptitudes in subsequent pinacol-pina
โฆ LIBER โฆ
Migratory aptitudes in pinacol rearrangement of vic-dihydroxychlorins
โ Scribed by C. K. Chang; Chariklia Sotiriou
- Book ID
- 112128081
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1985
- Tongue
- English
- Weight
- 176 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-152X
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## Abstract The migratory aptitude of the ethoxycarbonyl group in the pinacol rearrangement was deduced from the structure of the products observed after treatment of 2โsubstituted 2,3โdihydroxyโ3โphenylbutyrates with fluorosulfonic acid at 0ยฐ for 3 minutes. The migratory aptitude of ethoxycarbonyl
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