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The photoperoxidation of unsaturated organic molecules. Intersystem crossing in 9,10-diphenylanthracene

โœ Scribed by B. Stevens; L.E. Mills

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
189 KB
Volume
15
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Measurements of the quantum yieId of 9,lO-diphcnyIanthracene autoperosidation as a function of dissolved osygtzn concentration in benzene at 25'C are consistent with an intersystem crossin yield of 0.13 + 0.03 for this molecule 2nd the absence of the Spiro-~Ilo~v~d esothermic process SI f 02 3X + TI + Oz IA. Thes: conclusions in-

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Spectroscopic determination of the most
Spectroscopic determination of the most probable intersystem crossing route in phosphorescing molecules
โœ M.A. El-Sayed; D.S. Tinti; D.V. Owens ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 387 KB

A spectroscopic method employing steady-state optical techniques is described to detect spin polarization and to determine the most probable route of the intersystem crossing process in phosphorescing molecules. The method is based on observing ctiges as a function of temperature (ZC low Wmperature