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Spectroscopic determination of the most probable intersystem crossing route in phosphorescing molecules

✍ Scribed by M.A. El-Sayed; D.S. Tinti; D.V. Owens


Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
387 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis


A spectroscopic method employing steady-state optical techniques is described to detect spin polarization and to determine the most probable route of the intersystem crossing process in phosphorescing molecules.

The method is based on observing ctiges as a function of temperature (ZC low Wmperatures) in the relative intensiw of the vibronic bands of the phosphorescence spectrum.