The photoperoxidation of unsaturated organic molecules: VIII. The effect of biacetyl
β Scribed by Brian Stevens; Steven R. Perez
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 393 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0047-2670
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Measurements of the quantum yieId of 9,lO-diphcnyIanthracene autoperosidation as a function of dissolved osygtzn concentration in benzene at 25'C are consistent with an intersystem crossin yield of 0.13 + 0.03 for this molecule 2nd the absence of the Spiro-~Ilo~v~d esothermic process SI f 02 3X + TI
The static and frequency-dependent first hyperpolarisabilities ( p ) of three phenoxidepyridinium derivatives and Reichardt's betaine (ET30) have been computed in the gas phase and in aqueous solvent. The sum-over-states formalism is used to calculate individual components of the ptensors. The solve