The kinetics of the gas-phase thermal reaction between CFz(0F)z and CO has been studied in a static system a t temperatures ranging between 110 and 140Β°C. The only reaction products were CFz0 and Con, giving the following stoichiometry: The reaction is homogeneous. The rate is strictly second order
The photolysis of bis(fluoroxy)difluoromethane (CF2(OF)2) and its photochemical reaction with carbon monoxide
β Scribed by A.E. Croce; E. Castellano
- Book ID
- 103491438
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 582 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0047-2670
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π SIMILAR VOLUMES
Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500Β°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 Β± 0.03
CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 Ο³ 356 K u