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The photoelectron spectrum of an unstable species in the pyrolysis products of dimethyldisulphide

โœ Scribed by H.W. Kroto; R.J. Suffolk

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
216 KB
Volume
15
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A new photoelectron spectrum has been observed in the pyrolysis products of dimethyldisulphide, CHaSSCH3. As the major product under these conditions is known to be the unstable species thioformaldehyde, H2CS, the new spectrum has been assigned to this molecule. The first ionisation potential is 9.34 -+ 0.01 eV which compares well with the result obtained by other techniques. The evidence for this assignment is discussed.

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