A new photoelectron spectrum has been observed in the pyrolysis products of dimethyldisulphide, CHaSSCH3. As the major product under these conditions is known to be the unstable species thioformaldehyde, H2CS, the new spectrum has been assigned to this molecule. The first ionisation potential is 9.3
The photoelectron spectrum of a short-lived species in the decomposition products of CS2
β Scribed by G.H. King; H.W. Kroto; R.J. Suffolk
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 156 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The combination of laser ablation with laser-induced Β―uorescence (LIF) spectroscopy for the study of short-lived metal-containing molecules in the gas phase is reviewed. Results for two free radicals derived from the alkaline-earth metals, MgCCH and BaOH, have been chosen to illustrate these experim
A novel emission spectrum extending from 5500 to 8600 A has been observed during the gas-phase reaction of F2 with CS2. Long progressions in the lower-state (presumably the ground-state) bending frequency and shorter progressions in a ground-state stretching frequency were observed. A partial vibrat