✦ LIBER ✦

A new molecular electronic emission spectrum observed in the reaction of F2 with CS2

✍ Scribed by Robert J. Glinskp

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 314 KB
Volume: 129
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80355-4

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✦ Synopsis

A novel emission spectrum extending from 5500 to 8600 A has been observed during the gas-phase reaction of F2 with CS2. Long progressions in the lower-state (presumably the ground-state) bending frequency and shorter progressions in a ground-state stretching frequency were observed. A partial vibrational analysis is reported, from which two new frequencies are obtained: v; = 356 + 5 and v: = 83 1 k 8 cm-'.The electronic origin lies near 18500f 1200 cm-'. The spectrum is tentatively assigned to the FCS radical.

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