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The photochemistry of indenyl alcohols and esters: Substituent effects on the competition between ion- and radical-derived products

✍ Scribed by Pincock, J A; Young, I S


Book ID
120584458
Publisher
NRC Research Press
Year
2003
Tongue
French
Weight
494 KB
Volume
81
Category
Article
ISSN
0008-4042

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Substituent effect on regioselectivity i
✍ Nermin S Ünaldi; Metin Balci πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 65 KB

2,3-and 2,5-Dicyanobenzobarrelenes 5 and 6 have been synthesized and subjected to triplet-sensitized photoisomerization. 2,3-Dicyanobenzobarrelene 5 gave two di-p-methane rearrangement products 7 and 8 and a [2p+2p]-cycloaddition product 9. However, 2,5-dicyanobenzobarrelene 6 formed a single di-p-m