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On the distinction between radical chemistry and Gif chemistry competitive oxidation of alkanes and sec.-alcohols

✍ Scribed by Derek H.R. Barton; Valérie N. Le Gloahec

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
177 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

By compming the reactivities of alcohols and IIImnes towards TBI-IP radical oxidation and non-radical Gif oxidation, we bring additional evidence regarding the non-radical nature of Gif chemistry.

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Normalized data for cyclooctane and for cyclndndecane are compared with cyciohexane as unity. In radical chemisuy cyclooctane is 2-3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexune is more reactive than cyclooctane or cyclndo~\_\_\_~e. Thus by simple competitive experiments a