By compming the reactivities of alcohols and IIImnes towards TBI-IP radical oxidation and non-radical Gif oxidation, we bring additional evidence regarding the non-radical nature of Gif chemistry.
On the distinction between radical chemistry and Gif chemistry
✍ Scribed by Derek H.R. Barton; Franck Launay; Valérie N. Le Gloahec; Tingsheng Li; Frances Smith
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 193 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Normalized data for cyclooctane and for cyclndndecane are compared with cyciohexane as unity. In radical chemisuy cyclooctane is 2-3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexune is more reactive than cyclooctane or cyclndo~___~e. Thus by simple competitive experiments a distinction between radical chemistry and Gif chemistry can be made.
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