Substituent effects on the stability of three-electron-bonded radicals and radical ions from organic sulfur compounds
β Scribed by Goebl, Manfred; Bonifacic, Marija; Asmus, Klaus Dieter
- Book ID
- 126197996
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 621 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Products and kinetics of the homolytic thermolyses reactions of the three tertiary amides 6a-c of 2,3,3-triphenylpropanoic acid were studied in solution. The steric effects on the C-C bond homolysis processes were evaluated from MM2 calcu-lations. Taking this into account, we deduced radical stabili
## Abstract The thermolysis reactions of 3a and 2a, b were studied over a temperature range of 40Β°C and the activation parameters were determined. They were compared with the activation parameters of structurally comparable hydrocarbons of similar strain in order to obtain the radical stabilization