ChemInform Abstract: Substituent Effects on the C-C Bond Strength. Part 19. Geminal Substituent Effects. Part 10. Radical Stabilization Enthalpies of . alpha.,α-Bis(methoxycarbonyl)alkyl and Tris(methoxycarbonyl) methyl Radicals.

Substituent Effects on the CC Bond Stre

Substituent Effects on the CC Bond Strength, 20. – Geminal Substituent Effects, 14. – Stabilization of the Cyano(dimethylamino)methyl Radical – Synergistic effect Due to Interaction Between α-Amino and α-Cyano Groups on the Radical Stabilization Energy

✍ Welle, Frank M. ;Verevkin, Sergey P. ;Beckhaus, Hans-Dieter ;Rüchardt, Christoph 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 913 KB

## Abstract The thermolysis reactions of 3a and 2a, b were studied over a temperature range of 40°C and the activation parameters were determined. They were compared with the activation parameters of structurally comparable hydrocarbons of similar strain in order to obtain the radical stabilization