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The photochemical addition of alkenes to N-methylphthalimide evidence for electron transfer quenching

โœ Scribed by Paul H. Mazzocchi; Saeko Minamikawa; Paul Wilson

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
189 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

We reported the photochemical addition of dienes' and alkenes' to N-methylphthalimide (NMP) to give 3,4-benzo-6,7-dihydro-1-methylazepine-2,5-diones in what is formally a ~12 + u 2 addition of an alkene to the C(O)-N bond in the imide. The reaction was found to be regiospecific with respect to the direction

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The photochemical reaction of cerium(IV)
The photochemical reaction of cerium(IV) ammonium nitrate with alkenes. Rate and mechanism for the addition of the nitrate radical to alkenes
โœ E. Baciocchi; T. Del Giacco; S.M. Murgia; G.V. Sebastiani ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 884 KB

The photochemical reaction of cerium(IV) ammonium nitrate (CAN) in acetonitrile with cyclohexene, I-octene and a series of styrene derivatives leads to the formation of 1,2--dlnitrate adducts in high yields. The reaction takes place by the intermediacy of the nitrate radical which forms in the photo