✦ LIBER ✦

The first reported evidence of single electron transfer in the 1,2-addition of primary Grignard reagents to ketones

✍ Scribed by E.C. Ashby; J. Bowers; Robert Depriest

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 114 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(80)80229-2

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

New methodology in determining evidence

New methodology in determining evidence for single electron transfer in the reaction of Grignard reagents with ketones

✍ Yunshi Zhang; Bernd Wenderoth; Wei-Yang Su; E.C. Ashby 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 616 KB

The Stereochemistry of the 1,2-Addition

The Stereochemistry of the 1,2-Addition of Grignard Reagents to Some Steroidal Unsaturated Ketones.

✍ Cavit Uyanik; James R. Hanson; Peter B. Hitchcock 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 99 KB

Regioselectivity in the Addition of Grig

Regioselectivity in the Addition of Grignard Reagents to Bis(2-benzothiazolyl) Ketone: C- vs. O-Alkylation Using Aryl Grignard Reagents

✍ Carla Boga; Gabriele Micheletti 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

Competition between nucleophilic additio

Competition between nucleophilic addition and electron-transfer process in the reaction of 9-diazo-10-anthrone with grignard reagents

✍ Paolo Bruni; Patricia Carloni; Carla Conti; Elisabetta Giorgini; Lucedio Greci; 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 503 KB

Single electron transfer in the addition

Single electron transfer in the addition of chiral dipole-stabilized organolithiums to carbonyls. Stereochemistry of a chiral nucleophile as a mechanistic probe

✍ Kathleen S. Rein; Zhi-Hong Chen; P.T. Perumal; Luis Echegoyen; Robert E. Gawley 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 183 KB

Silver Compounds in Synthetic Chemistry.

Silver Compounds in Synthetic Chemistry. 1 A Facile Preparative Route for Pentafluorophenylsilver, AgC6F5 and its Use as an Oxidative Pentafluorophenyl Group Transfer Reagent in Reactions with Group 12 to 16 Elements — the Single Crystal Structure of AgC6F5 · EtCN, the First Arylsilver Derivative Crystallising in Infinite Chains

✍ Wieland Tyrra; Mathias S. Wickleder 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c