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The photochemical addition of aldehydes to vinylsilanes

✍ Scribed by N. V. Komarov; V. K. Roman; L. I. Komarova

Book ID
112488230
Publisher
Springer
Year
1966
Tongue
English
Weight
202 KB
Volume
15
Category
Article
ISSN
1573-9171

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A zincated N,N-dimethylhydrazone of a ketone bearing a BuZn(II) countercation undergoes intermolecular addition to a vinylsilane to afford the hydrazone of a 2-(2-silylethyl)ketone in good yield, providing a new synthetic route to functionalized carbonyl compounds.