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Study of the addition of diazoles to vinylsilanes

✍ Scribed by V. D. Sheludyakov; N. E. Kuz’mina; A. M. Abramkin; D. A. Cheshkov; P. A. Storozhenko


Book ID
111461235
Publisher
Springer
Year
2011
Tongue
English
Weight
339 KB
Volume
81
Category
Article
ISSN
1070-3632

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✍ Eiichi Nakamura; Katsumi Kubota 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 246 KB

A zincated N,N-dimethylhydrazone of a ketone bearing a BuZn(II) countercation undergoes intermolecular addition to a vinylsilane to afford the hydrazone of a 2-(2-silylethyl)ketone in good yield, providing a new synthetic route to functionalized carbonyl compounds.