The olefinic aldol reaction. Addition of zincated hydrazone to vinylsilane
โ Scribed by Eiichi Nakamura; Katsumi Kubota
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 246 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
A zincated N,N-dimethylhydrazone of a ketone bearing a BuZn(II) countercation undergoes intermolecular addition to a vinylsilane to afford the hydrazone of a 2-(2-silylethyl)ketone in good yield, providing a new synthetic route to functionalized carbonyl compounds.
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