The phase transition in the 1:1 CT-complex anthracene/TCNB at 206 K. A NMR study
✍ Scribed by Auch, W. ;Steudle, W. ;Von Schütz, J. U. ;Wolf, H. C.
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 362 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0031-8965
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The optical emission of the CT complex anthracenels-tetracyanoben,ene (A/TCNB) was investkated between 1.2 K and 300 K. Delayed fluorescence was observed in the whole temperature range. provin, 0 the existence of mobile triplet e\crtons even at 1.2 K. Prompt and delayed fluorescence show a remarkabl
We have found a new low-lying CT triplet excitation wirh nn\* character in very thoroughly purified crystals of the i : 1 ## CT comples of anthracene/TCNB. This contention is supported by the results of time-resolved and steady-srare ODMR esperiments.