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Optical/ESR studies of the 1 : 1 CT crytal anthracene/TCNB at 1.2 K: Evidence for nπ* triplet excitations

✍ Scribed by F.C. Bos; J. Schmidt

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 628 KB
Volume: 108
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85056-3

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✦ Synopsis

We have found a new low-lying CT triplet excitation wirh nn* character in very thoroughly purified crystals of the i : 1

CT comples of anthracene/TCNB.

This contention is supported by the results of time-resolved and steady-srare ODMR esperiments.

📜 SIMILAR VOLUMES

Optical studies of the 1:1 CT crystal an

Optical studies of the 1:1 CT crystal anthracene/TCNB: Mobile triplet excitons at 1.2 K

✍ W. Steudle; J.U. Von Schütz; H. Möhwald 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 455 KB

The optical emission of the CT complex anthracenels-tetracyanoben,ene (A/TCNB) was investkated between 1.2 K and 300 K. Delayed fluorescence was observed in the whole temperature range. provin, 0 the existence of mobile triplet e\crtons even at 1.2 K. Prompt and delayed fluorescence show a remarkabl