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The PdCl2/R3SiH system for the silylation of nucleosides

✍ Scribed by Carla Ferreri; Cristina Costantino; Roberto Romeo; Chryssostomos Chatgilialoglu

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
227 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Convenient syntheses of TIPDS-C12 and TBDMS-Br from the corresponding hydrides were obtained by using catalytic PdCL 2 and CCI 4 or CH2Br 2, respectively. These systems can be successfully applied in tandem procedures for improved silylation of nucleosides.

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