The oxidative coupling of 2,6-dimethylphenol catalyzed by basic copper(II) complexes
โ Scribed by Shigeru Tsuruya; Toru Takaki; Mitsuo Masai
- Book ID
- 113177586
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 778 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0021-9517
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๐ SIMILAR VOLUMES
The oxidative coupling reaction of 2,6dimethylphenol (DMP) with H 2 O 2 catalyzed by four copper(II) complexes was investigated in Tris-HNO 3 buffer solution at 25 C. The kinetics of formation of diphenoquinone (DPQ, 4-(3,5-dimethyl-4-oxo-2,5-cyclohexadienylidene)-2,6-dimethyl-2,5-cyclohexadienone)
The oxidative coupling polymerization of 2,6-dimethylphenol (DMP) catalysed by copper(II) complexes of N-methylimidazole in toluene/iso-propanol (13/2v/v) or 1,2-dichlorobenzene/methanol (ODCB/MeOH) (13/2 v/v) was investigated. EPR spectra of these complexes indicated that the complex had a mononucl