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Basic copper(II) complex catalyzed oxidative coupling of 2,6-dialkylphenols

โœ Scribed by Shigeru Tsuruya; Kazunori Kinumi; Kazuhiko Hagi; Mitsuo Masai

Publisher
Elsevier Science
Year
1983
Weight
930 KB
Volume
22
Category
Article
ISSN
0304-5102

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๐Ÿ“œ SIMILAR VOLUMES

Oxidative coupling of 2,6-dimethylphenol
Oxidative coupling of 2,6-dimethylphenol catalyzed by copper(II) complexes in aqueous solution
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The oxidative coupling reaction of 2,6dimethylphenol (DMP) with H 2 O 2 catalyzed by four copper(II) complexes was investigated in Tris-HNO 3 buffer solution at 25 C. The kinetics of formation of diphenoquinone (DPQ, 4-(3,5-dimethyl-4-oxo-2,5-cyclohexadienylidene)-2,6-dimethyl-2,5-cyclohexadienone)

Oxidative coupling polymerization of 2,6
Oxidative coupling polymerization of 2,6-dimethylphenol catalysed by copper(II) complexes of n-methylimidazole
โœ Wei Chen; Ger Challa ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 448 KB

The oxidative coupling polymerization of 2,6-dimethylphenol (DMP) catalysed by copper(II) complexes of N-methylimidazole in toluene/iso-propanol (13/2v/v) or 1,2-dichlorobenzene/methanol (ODCB/MeOH) (13/2 v/v) was investigated. EPR spectra of these complexes indicated that the complex had a mononucl