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The oxidative coupling reaction of 2,6-dimethylphenol with heterogeneous basic copper(II) catalysts

✍ Scribed by Shigeru Tsuruya; Kenji Nakamae; Teijiro Yonezawa


Book ID
113175407
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
750 KB
Volume
44
Category
Article
ISSN
0021-9517

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Oxidative coupling of 2,6-dimethylphenol
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The oxidative coupling reaction of 2,6dimethylphenol (DMP) with H 2 O 2 catalyzed by four copper(II) complexes was investigated in Tris-HNO 3 buffer solution at 25 C. The kinetics of formation of diphenoquinone (DPQ, 4-(3,5-dimethyl-4-oxo-2,5-cyclohexadienylidene)-2,6-dimethyl-2,5-cyclohexadienone)