The oxidation of Cu(I) in electrolyte solutions
β Scribed by Virender K. Sharma; Frank J. Millero
- Book ID
- 104864537
- Publisher
- Springer US
- Year
- 1988
- Tongue
- English
- Weight
- 745 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0095-9782
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The homogeneous oxidation of cuprous chloride in 2 M NaCl solutions by dissolved molecular oxygen was studied, using a batch reactor, at constant pH and temperature. The rate of homogeneous reaction is represented by the expression: R = k[O,] [CU(I)]'.~ with k = 2.8 x 106cm4-5mol-' 's-l where square
The oxidation potentials, E,,, of several solutions of interest for nonaqueous Li cells have been measured by linear sweep voltammetric experiments. A correlation is found between E,, and the basicity of the solvents, expressed by their donor numbers (DN). Esters and sulfones have higher resistance